|
|
実際の測定温度 |
|
|
|
|
|
aldehyde or |
合計値 |
|
|
|
|
|
a-pyr |
b-pyr |
a-fur |
b-fur |
keton |
|
|
アルドヘキソース |
D-Glucose |
31℃ |
存在比 |
37.3 |
62.6 |
― |
0.1 |
0.002 |
100.002 |
「糖質の科学」表2.3 |
分子量 180.16 |
Df Gi (kJ/ K mol) |
|
r |
0.37299254 |
0.62598748 |
|
0.00099998 |
1.99996E-05 |
|
|
|
-915.9 |
|
RT r lnr |
-0.911874418 |
-0.726903732 |
|
-0.017123825 |
-0.000536428 |
-1.656438403 |
混合エントロピー項 |
|
|
|
(Df Gi) |
-24.37720292 |
-25.66074406 |
|
-9.69778767 |
0 |
|
|
|
|
|
(r Df Gi) |
-9.092514841 |
-16.06330451 |
|
-0.009697594 |
0 |
-25.16551695 |
-26.82195535 |
|
-915.9 |
|
Df Gi |
-913.4552476 |
-914.7387887 |
|
-898.7758323 |
-889.0780446 |
|
|
|
|
|
r Df Gi |
-340.7119931 |
-572.6150294 |
|
-0.898757857 |
-0.017781205 |
-914.2435616 |
-915.9 |
|
|
|
|
|
|
|
|
|
|
|
|
D-Mannose |
36℃ |
存在比 |
63.7 |
35.5 |
0.6 |
0.2 |
― |
|
「糖質の科学」表2.3 |
|
Df Gi (kJ/ K mol) |
|
相対比 |
5.9241 |
3.3015 |
0.0558 |
0.0186 |
― |
9.3 |
|
|
-910 |
|
Dm |
-20.21350957 |
-18.73510039 |
-8.417098308 |
-5.639037414 |
― |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
D-Mannose |
36℃ |
存在比 |
63.24 |
35.96 |
0.55 |
0.25 |
0.0064 |
100.0064 |
「単糖類の化学」表3.3 |
|
Df Gi (kJ/ K mol) |
|
r |
0.632359529 |
0.359576987 |
0.005499648 |
0.00249984 |
6.39959E-05 |
1 |
|
|
-910 |
|
RT r lnr |
-0.718426784 |
-0.911728085 |
-0.070935876 |
-0.037129672 |
-0.001531975 |
-1.739752393 |
混合エントロピー項 |
|
|
|
(Df Gi) |
-22.80254352 |
-21.40309108 |
-11.04039108 |
-9.085828942 |
0 |
|
|
|
|
|
(r Df Gi) |
-14.41940568 |
-7.696059003 |
-0.060718265 |
-0.022713119 |
0 |
-22.19889607 |
-23.93864846 |
|
-910 |
|
Df Gi |
-908.8638951 |
-907.4644426 |
-897.1017426 |
-895.1471805 |
-886.0613515 |
|
|
|
|
|
r Df Gi |
-574.7287446 |
-326.3033302 |
-4.933743825 |
-2.237724737 |
-0.056704297 |
-908.2602476 |
-910 |
|
|
|
|
|
|
|
|
|
|
|
|
D-Allose |
31℃ |
存在比 |
14 |
77.5 |
3.5 |
5 |
0.01 |
100.01 |
Dictionary of Natural Products, Chapman & Hall (1994). |
|
Df Gi (kJ/ K mol) |
|
r |
0.139986001 |
0.774922508 |
0.0349965 |
0.049995 |
9.999E-05 |
1 |
|
|
-910.34 |
|
RT r lnr |
-0.682317342 |
-0.489842562 |
-0.290847683 |
-0.371291787 |
-0.002283012 |
-1.836582387 |
混合エントロピー項 |
|
|
|
(Df Gi) |
-17.95822268 |
-22.20028723 |
-14.52164055 |
-15.40582704 |
0 |
|
|
|
|
|
(r Df Gi) |
-2.513899786 |
-17.20350225 |
-0.508206599 |
-0.77021433 |
0 |
-20.99582297 |
-22.83240536 |
|
-910.34 |
|
Df Gi |
-905.4658173 |
-909.7078819 |
-902.0292352 |
-902.9134217 |
-887.5075946 |
|
|
|
|
|
r Df Gi |
-126.7525392 |
-704.9531131 |
-31.56786645 |
-45.14115697 |
-0.088741885 |
-908.5034176 |
-910.34 |
|
|
|
|
|
|
|
|
|
|
|
|
D-Altrose |
22 ℃ |
存在比 |
27 |
43 |
17 |
13 |
0.04 |
100.04 |
|
|
Df Gi (kJ/ K mol) |
|
r |
0.269892043 |
0.429828069 |
0.169932027 |
0.129948021 |
0.00039984 |
1 |
|
|
-908.05 |
|
RT r lnr |
-0.876282628 |
-0.899702305 |
-0.746616625 |
-0.657359946 |
-0.007755524 |
-3.187717028 |
混合エントロピー項 |
|
|
|
(Df Gi) |
-16.14977732 |
-17.30339885 |
-15.00294749 |
-14.33792911 |
0 |
|
|
|
|
|
(r Df Gi) |
-4.358696398 |
-7.437486513 |
-2.54948128 |
-1.86318551 |
0 |
-16.2088497 |
-19.39656673 |
|
-908.05 |
|
Df Gi |
-904.8032106 |
-905.9568321 |
-903.6563808 |
-902.9913624 |
-888.6534333 |
|
|
|
|
|
r Df Gi |
-244.1991872 |
-389.4056755 |
-153.5601607 |
-117.3419403 |
-0.355319246 |
-904.862283 |
-908.05 |
|
|
|
|
|
|
|
|
|
|
|
|
D-Galactose |
31℃ |
存在比 |
30 |
64 |
2.5 |
3.5 |
0.02 |
100.02 |
「糖質の科学」表2.3 |
|
Df Gi (kJ/ K mol) |
|
r |
0.299940012 |
0.639872026 |
0.024995001 |
0.034993001 |
0.00019996 |
1 |
|
|
-908.93 |
|
RT r lnr |
-0.895353391 |
-0.708228328 |
-0.228582215 |
-0.290827278 |
-0.004222028 |
-2.12721324 |
混合エントロピー項 |
|
|
|
(Df Gi) |
-18.12925394 |
-20.00753407 |
-11.96924491 |
-12.80334949 |
0 |
|
|
|
|
|
(r Df Gi) |
-5.437688645 |
-12.80226135 |
-0.299171288 |
-0.448027626 |
0 |
-18.98714891 |
-21.11436215 |
|
-908.93 |
|
Df Gi |
-905.9448918 |
-907.8231719 |
-899.7848828 |
-900.6189873 |
-887.8156378 |
|
|
|
|
|
r Df Gi |
-271.7291217 |
-580.8906519 |
-22.49012404 |
-31.51536148 |
-0.177527622 |
-906.8027868 |
-908.93 |
|
|
|
|
|
|
|
|
|
|
|
|
D-Talose |
22 ℃ |
|
42 |
29 |
16 |
13 |
0.03 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
D-Gulose |
22 ℃ |
|
16 |
81 |
- |
3 |
- |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
D-Idose |
31℃ |
|
38.5 |
36 |
11.5 |
14 |
0.2 |
|
|
|
|
|
|
|
|
|
|
|
|
|
ケトヘキソース |
D-Fructose |
30℃ |
|
2 |
70 |
5 |
23 |
0.7 |
|
Dictionary of Natural Products, Chapman & Hall (1994). |
分子量 180.16 |
|
31℃ |
存在比 |
2.5 |
65 |
6.5 |
25 |
0.8 |
99.8 |
|
|
Df Gi (kJ/ K mol) |
|
r |
0.0250501 |
0.651302605 |
0.065130261 |
0.250501002 |
0.008016032 |
1 |
|
|
-915.51 |
|
RT r lnr |
-0.228949364 |
-0.692292348 |
-0.440995326 |
-0.859624055 |
-0.095906068 |
-2.317767161 |
混合エントロピー項 |
|
|
|
(Df Gi) |
-2.824623405 |
-10.90134698 |
-5.193307612 |
-8.532662773 |
0 |
|
|
|
|
|
(r Df Gi) |
-0.070757099 |
-7.100075688 |
-0.338241478 |
-2.137440574 |
0 |
-9.64651484 |
-11.964282 |
|
-915.51 |
|
Df Gi |
-906.3703414 |
-914.447065 |
-908.7390256 |
-912.0783808 |
-903.545718 |
|
|
|
|
|
r Df Gi |
-22.70466787 |
-595.5817557 |
-59.18640948 |
-228.4765483 |
-7.242851447 |
-913.1922328 |
-915.51 |
|
|
|
|
|
|
|
|
|
|
|
|
L-Sorbose |
31℃ |
存在比 |
93 |
2 |
4 |
1 |
0.3 |
100.3 |
Dictionary of Natural Products, Chapman & Hall (1994). |
|
Df Gi (kJ/ K mol) |
|
r |
0.927218345 |
0.019940179 |
0.039880359 |
0.00997009 |
0.002991027 |
1 |
|
|
-911.95 |
|
RT r lnr |
-0.173692426 |
-0.193523698 |
-0.318521331 |
-0.113893365 |
-0.043095066 |
-0.842725886 |
混合エントロピー項 |
|
|
|
(Df Gi) |
-14.22079063 |
-4.702903529 |
-6.421194595 |
-2.984612463 |
0 |
|
|
|
|
|
(r Df Gi) |
-13.18577795 |
-0.09377674 |
-0.256079545 |
-0.029756854 |
0 |
-13.56539109 |
-14.40811698 |
|
-911.95 |
|
Df Gi |
-911.7626737 |
-902.2447866 |
-903.9630776 |
-900.5264955 |
-897.541883 |
|
|
|
|
|
r Df Gi |
-845.4030773 |
-17.99092296 |
-36.05037199 |
-8.978329965 |
-2.684571933 |
-911.1072741 |
-911.95 |
|
|
|
|
|
|
|
|
|
|
|
|
D-Psicose |
27℃ |
存在比 |
22 |
24 |
39 |
15 |
0.3 |
100.3 |
Dictionary of Natural Products, Chapman & Hall (1994). |
|
Df Gi (kJ/ K mol) |
|
r |
0.219341974 |
0.239282154 |
0.3888335 |
0.149551346 |
0.002991027 |
1 |
|
|
-912.78 |
|
RT r lnr |
-0.824923889 |
-0.848304146 |
-0.910510058 |
-0.704436088 |
-0.043095066 |
-3.331269246 |
混合エントロピー項 |
|
|
|
(Df Gi) |
-10.64721397 |
-10.86291257 |
-12.06647188 |
-9.69778767 |
0 |
|
|
|
|
|
(r Df Gi) |
-2.335380931 |
-2.599301113 |
-4.691848486 |
-1.450317199 |
0 |
-11.07684773 |
-14.40811698 |
|
-912.78 |
|
Df Gi |
-909.019097 |
-909.2347956 |
-910.4383549 |
-908.0696707 |
-898.371883 |
|
|
|
|
|
r Df Gi |
-199.3860432 |
-217.56366 |
-354.0089316 |
-135.8030415 |
-2.687054486 |
-909.4487308 |
-912.78 |
|
|
|
|
|
|
|
|
|
|
|
|
D-Tagatose |
27℃ |
|
79 |
16 |
1 |
4 |
0.6 |
|
Dictionary of Natural Products, Chapman & Hall (1994). |
|
|
31℃ |
存在比 |
71 |
18 |
2.5 |
7.5 |
0.3 |
99.3 |
|
|
Df Gi (kJ/ K mol) |
|
相対比 |
0.715005035 |
0.181268882 |
0.025176234 |
0.075528701 |
0.003021148 |
1 |
|
|
-911.66 |
|
RT r lnr |
-0.594604902 |
-0.767405447 |
-0.229788713 |
-0.483669244 |
-0.04345401 |
-2.118922316 |
混合エントロピー項 |
|
|
|
(Df Gi) |
-13.551668 |
-10.14975734 |
-5.256069698 |
-7.979496604 |
0 |
|
|
|
|
|
(r Df Gi) |
-9.689510854 |
-1.839835167 |
-0.132328039 |
-0.602681012 |
0 |
-12.26435507 |
-14.38327739 |
|
-911.66 |
|
Df Gi |
-910.8283906 |
-907.42648 |
-902.5327923 |
-905.2562192 |
-897.2767226 |
|
|
|
|
|
r Df Gi |
-651.2468855 |
-164.4881837 |
-22.72237644 |
-68.37282622 |
-2.710805808 |
-909.5410777 |
-911.66 |