|
|
|
|
|
|
|
|
aldehyde or |
|
|
|
|
測定温度 |
|
a-pyr |
b-pyr |
a-fur |
b-fur |
keton |
|
|
アルドヘキソース |
D-Glucose |
31℃ |
存在比 |
37.3 |
62.6 |
― |
0.1 |
0.002 |
100.002 |
「糖質の科学」表2.3 |
分子量 180.16 |
|
|
Dm |
-24.86622792 |
-26.17551786 |
|
-9.892332574 |
0 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
D-Mannose |
36℃ |
存在比 |
63.7 |
35.5 |
0.6 |
0.2 |
― |
|
「糖質の科学」表2.3 |
|
|
|
相対比 |
5.9241 |
3.3015 |
0.0558 |
0.0186 |
― |
9.3 |
|
|
|
|
Dm |
-20.21350957 |
-18.73510039 |
-8.417098308 |
-5.639037414 |
― |
|
|
|
D-Mannose |
36℃ |
存在比 |
63.24 |
35.96 |
0.55 |
0.25 |
0.0064 |
|
「単糖類の化学」表3.3 |
|
|
|
相対比 |
5.88132 |
3.34428 |
0.05115 |
0.02325 |
0.0005952 |
9.3005952 |
|
|
|
|
Dm |
-20.19518269 |
-18.76765617 |
-8.197072639 |
-6.203300512 |
3.064796983 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
D-Allose |
31℃ |
存在比 |
14 |
77.5 |
3.5 |
5 |
0.01 |
|
Dictionary of Natural Products, Chapman & Hall (1994). |
|
|
|
相対比 |
1.7038 |
9.43175 |
0.42595 |
0.6085 |
0.001217 |
12.171217 |
|
|
|
|
Dm |
-17.06232524 |
-21.38948879 |
-13.55680269 |
-14.45872662 |
1.256152882 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
D-Altrose |
22 ℃ |
存在比 |
27 |
43 |
17 |
13 |
0.04 |
|
|
|
|
|
相対比 |
1.134 |
1.806 |
0.714 |
0.546 |
0.00168 |
4.20168 |
|
|
|
|
Dm |
-16.03286657 |
-17.20963062 |
-14.86303047 |
-14.18467133 |
0.44088741 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
D-Galactose |
31℃ |
存在比 |
30 |
64 |
2.5 |
3.5 |
0.02 |
|
「糖質の科学」表2.3 |
|
|
|
相対比 |
0.87 |
1.856 |
0.0725 |
0.1015 |
0.00058 |
2.90058 |
|
|
|
|
Dm |
-15.36272751 |
-17.27868734 |
-9.079144063 |
-9.929981408 |
3.130212884 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
D-Talose |
22 ℃ |
|
42 |
29 |
16 |
13 |
0.03 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
D-Gulose |
22 ℃ |
|
16 |
81 |
- |
3 |
- |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
D-Idose |
31℃ |
|
38.5 |
36 |
11.5 |
14 |
0.2 |
|
|
|
|
|
|
|
|
|
|
|
|
|
ケトヘキソース |
D-Fructose |
30℃ |
|
2 |
70 |
5 |
23 |
0.7 |
|
Dictionary of Natural Products, Chapman & Hall (1994). |
分子量 180.16 |
|
31℃ |
存在比 |
2.5 |
65 |
6.5 |
25 |
0.8 |
|
|
|
|
|
相対比 |
2.135 |
55.51 |
5.551 |
21.35 |
0.6832 |
85.2292 |
|
|
|
|
Dm |
-17.63281411 |
-25.87156282 |
-20.0490159 |
-23.45536103 |
-14.75152664 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
L-Sorbose |
31℃ |
存在比 |
93 |
2 |
4 |
1 |
0.3 |
|
Dictionary of Natural Products, Chapman & Hall (1994). |
|
|
|
相対比 |
18.879 |
0.406 |
0.812 |
0.203 |
0.0609 |
20.3609 |
|
|
|
|
Dm |
-23.14432702 |
-13.43550396 |
-15.18826523 |
-11.68274268 |
-8.638256653 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
D-Psicose |
27℃ |
存在比 |
22 |
24 |
39 |
15 |
0.3 |
|
Dictionary of Natural Products, Chapman & Hall (1994). |
|
|
|
相対比 |
6.248 |
6.816 |
11.076 |
4.26 |
0.0852 |
28.4852 |
|
|
|
|
Dm |
-20.34811893 |
-20.5681446 |
-21.79584822 |
-19.37964642 |
-9.48731385 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
D-Tagatose |
27℃ |
|
79 |
16 |
1 |
4 |
0.6 |
|
Dictionary of Natural Products, Chapman & Hall (1994). |
|
|
31℃ |
存在比 |
71 |
18 |
2.5 |
7.5 |
0.3 |
|
|
|
|
|
相対比 |
6.2338 |
1.5804 |
0.2195 |
0.6585 |
0.02634 |
8.71854 |
|
|
|
|
Dm |
-20.34236535 |
-16.87220981 |
-11.88035111 |
-14.65841201 |
-6.518840711 |
|
|