| 実際の測定温度 | aldehyde or | 合計値 | ||||||||
| a-pyr | b-pyr | a-fur | b-fur | keton | ||||||
| アルドヘキソース | D-Glucose | 31℃ | 存在比 | 37.3 | 62.6 | ― | 0.1 | 0.002 | 100.002 | 「糖質の科学」表2.3 |
| 分子量 180.16 | Df Gi (kJ/ K mol) | r | 0.37299254 | 0.62598748 | 0.00099998 | 1.99996E-05 | ||||
| -915.9 | RT r lnr | -0.911874418 | -0.726903732 | -0.017123825 | -0.000536428 | -1.656438403 | 混合エントロピー項 | |||
| (Df Gi) | -24.37720292 | -25.66074406 | -9.69778767 | 0 | ||||||
| (r Df Gi) | -9.092514841 | -16.06330451 | -0.009697594 | 0 | -25.16551695 | -26.82195535 | ||||
| -915.9 | Df Gi | -913.4552476 | -914.7387887 | -898.7758323 | -889.0780446 | |||||
| r Df Gi | -340.7119931 | -572.6150294 | -0.898757857 | -0.017781205 | -914.2435616 | -915.9 | ||||
| D-Mannose | 36℃ | 存在比 | 63.7 | 35.5 | 0.6 | 0.2 | ― | 「糖質の科学」表2.3 | ||
| Df Gi (kJ/ K mol) | 相対比 | 5.9241 | 3.3015 | 0.0558 | 0.0186 | ― | 9.3 | |||
| -910 | Dm | -20.21350957 | -18.73510039 | -8.417098308 | -5.639037414 | ― | ||||
| D-Mannose | 36℃ | 存在比 | 63.24 | 35.96 | 0.55 | 0.25 | 0.0064 | 100.0064 | 「単糖類の化学」表3.3 | |
| Df Gi (kJ/ K mol) | r | 0.632359529 | 0.359576987 | 0.005499648 | 0.00249984 | 6.39959E-05 | 1 | |||
| -910 | RT r lnr | -0.718426784 | -0.911728085 | -0.070935876 | -0.037129672 | -0.001531975 | -1.739752393 | 混合エントロピー項 | ||
| (Df Gi) | -22.80254352 | -21.40309108 | -11.04039108 | -9.085828942 | 0 | |||||
| (r Df Gi) | -14.41940568 | -7.696059003 | -0.060718265 | -0.022713119 | 0 | -22.19889607 | -23.93864846 | |||
| -910 | Df Gi | -908.8638951 | -907.4644426 | -897.1017426 | -895.1471805 | -886.0613515 | ||||
| r Df Gi | -574.7287446 | -326.3033302 | -4.933743825 | -2.237724737 | -0.056704297 | -908.2602476 | -910 | |||
| D-Allose | 31℃ | 存在比 | 14 | 77.5 | 3.5 | 5 | 0.01 | 100.01 | Dictionary of Natural Products, Chapman & Hall (1994). | |
| Df Gi (kJ/ K mol) | r | 0.139986001 | 0.774922508 | 0.0349965 | 0.049995 | 9.999E-05 | 1 | |||
| -910.34 | RT r lnr | -0.682317342 | -0.489842562 | -0.290847683 | -0.371291787 | -0.002283012 | -1.836582387 | 混合エントロピー項 | ||
| (Df Gi) | -17.95822268 | -22.20028723 | -14.52164055 | -15.40582704 | 0 | |||||
| (r Df Gi) | -2.513899786 | -17.20350225 | -0.508206599 | -0.77021433 | 0 | -20.99582297 | -22.83240536 | |||
| -910.34 | Df Gi | -905.4658173 | -909.7078819 | -902.0292352 | -902.9134217 | -887.5075946 | ||||
| r Df Gi | -126.7525392 | -704.9531131 | -31.56786645 | -45.14115697 | -0.088741885 | -908.5034176 | -910.34 | |||
| D-Altrose | 22 ℃ | 存在比 | 27 | 43 | 17 | 13 | 0.04 | 100.04 | ||
| Df Gi (kJ/ K mol) | r | 0.269892043 | 0.429828069 | 0.169932027 | 0.129948021 | 0.00039984 | 1 | |||
| -908.05 | RT r lnr | -0.876282628 | -0.899702305 | -0.746616625 | -0.657359946 | -0.007755524 | -3.187717028 | 混合エントロピー項 | ||
| (Df Gi) | -16.14977732 | -17.30339885 | -15.00294749 | -14.33792911 | 0 | |||||
| (r Df Gi) | -4.358696398 | -7.437486513 | -2.54948128 | -1.86318551 | 0 | -16.2088497 | -19.39656673 | |||
| -908.05 | Df Gi | -904.8032106 | -905.9568321 | -903.6563808 | -902.9913624 | -888.6534333 | ||||
| r Df Gi | -244.1991872 | -389.4056755 | -153.5601607 | -117.3419403 | -0.355319246 | -904.862283 | -908.05 | |||
| D-Galactose | 31℃ | 存在比 | 30 | 64 | 2.5 | 3.5 | 0.02 | 100.02 | 「糖質の科学」表2.3 | |
| Df Gi (kJ/ K mol) | r | 0.299940012 | 0.639872026 | 0.024995001 | 0.034993001 | 0.00019996 | 1 | |||
| -908.93 | RT r lnr | -0.895353391 | -0.708228328 | -0.228582215 | -0.290827278 | -0.004222028 | -2.12721324 | 混合エントロピー項 | ||
| (Df Gi) | -18.12925394 | -20.00753407 | -11.96924491 | -12.80334949 | 0 | |||||
| (r Df Gi) | -5.437688645 | -12.80226135 | -0.299171288 | -0.448027626 | 0 | -18.98714891 | -21.11436215 | |||
| -908.93 | Df Gi | -905.9448918 | -907.8231719 | -899.7848828 | -900.6189873 | -887.8156378 | ||||
| r Df Gi | -271.7291217 | -580.8906519 | -22.49012404 | -31.51536148 | -0.177527622 | -906.8027868 | -908.93 | |||
| D-Talose | 22 ℃ | 42 | 29 | 16 | 13 | 0.03 | ||||
| D-Gulose | 22 ℃ | 16 | 81 | - | 3 | - | ||||
| D-Idose | 31℃ | 38.5 | 36 | 11.5 | 14 | 0.2 | ||||
| ケトヘキソース | D-Fructose | 30℃ | 2 | 70 | 5 | 23 | 0.7 | Dictionary of Natural Products, Chapman & Hall (1994). | ||
| 分子量 180.16 | 31℃ | 存在比 | 2.5 | 65 | 6.5 | 25 | 0.8 | 99.8 | ||
| Df Gi (kJ/ K mol) | r | 0.0250501 | 0.651302605 | 0.065130261 | 0.250501002 | 0.008016032 | 1 | |||
| -915.51 | RT r lnr | -0.228949364 | -0.692292348 | -0.440995326 | -0.859624055 | -0.095906068 | -2.317767161 | 混合エントロピー項 | ||
| (Df Gi) | -2.824623405 | -10.90134698 | -5.193307612 | -8.532662773 | 0 | |||||
| (r Df Gi) | -0.070757099 | -7.100075688 | -0.338241478 | -2.137440574 | 0 | -9.64651484 | -11.964282 | |||
| -915.51 | Df Gi | -906.3703414 | -914.447065 | -908.7390256 | -912.0783808 | -903.545718 | ||||
| r Df Gi | -22.70466787 | -595.5817557 | -59.18640948 | -228.4765483 | -7.242851447 | -913.1922328 | -915.51 | |||
| L-Sorbose | 31℃ | 存在比 | 93 | 2 | 4 | 1 | 0.3 | 100.3 | Dictionary of Natural Products, Chapman & Hall (1994). | |
| Df Gi (kJ/ K mol) | r | 0.927218345 | 0.019940179 | 0.039880359 | 0.00997009 | 0.002991027 | 1 | |||
| -911.95 | RT r lnr | -0.173692426 | -0.193523698 | -0.318521331 | -0.113893365 | -0.043095066 | -0.842725886 | 混合エントロピー項 | ||
| (Df Gi) | -14.22079063 | -4.702903529 | -6.421194595 | -2.984612463 | 0 | |||||
| (r Df Gi) | -13.18577795 | -0.09377674 | -0.256079545 | -0.029756854 | 0 | -13.56539109 | -14.40811698 | |||
| -911.95 | Df Gi | -911.7626737 | -902.2447866 | -903.9630776 | -900.5264955 | -897.541883 | ||||
| r Df Gi | -845.4030773 | -17.99092296 | -36.05037199 | -8.978329965 | -2.684571933 | -911.1072741 | -911.95 | |||
| D-Psicose | 27℃ | 存在比 | 22 | 24 | 39 | 15 | 0.3 | 100.3 | Dictionary of Natural Products, Chapman & Hall (1994). | |
| Df Gi (kJ/ K mol) | r | 0.219341974 | 0.239282154 | 0.3888335 | 0.149551346 | 0.002991027 | 1 | |||
| -912.78 | RT r lnr | -0.824923889 | -0.848304146 | -0.910510058 | -0.704436088 | -0.043095066 | -3.331269246 | 混合エントロピー項 | ||
| (Df Gi) | -10.64721397 | -10.86291257 | -12.06647188 | -9.69778767 | 0 | |||||
| (r Df Gi) | -2.335380931 | -2.599301113 | -4.691848486 | -1.450317199 | 0 | -11.07684773 | -14.40811698 | |||
| -912.78 | Df Gi | -909.019097 | -909.2347956 | -910.4383549 | -908.0696707 | -898.371883 | ||||
| r Df Gi | -199.3860432 | -217.56366 | -354.0089316 | -135.8030415 | -2.687054486 | -909.4487308 | -912.78 | |||
| D-Tagatose | 27℃ | 79 | 16 | 1 | 4 | 0.6 | Dictionary of Natural Products, Chapman & Hall (1994). | |||
| 31℃ | 存在比 | 71 | 18 | 2.5 | 7.5 | 0.3 | 99.3 | |||
| Df Gi (kJ/ K mol) | 相対比 | 0.715005035 | 0.181268882 | 0.025176234 | 0.075528701 | 0.003021148 | 1 | |||
| -911.66 | RT r lnr | -0.594604902 | -0.767405447 | -0.229788713 | -0.483669244 | -0.04345401 | -2.118922316 | 混合エントロピー項 | ||
| (Df Gi) | -13.551668 | -10.14975734 | -5.256069698 | -7.979496604 | 0 | |||||
| (r Df Gi) | -9.689510854 | -1.839835167 | -0.132328039 | -0.602681012 | 0 | -12.26435507 | -14.38327739 | |||
| -911.66 | Df Gi | -910.8283906 | -907.42648 | -902.5327923 | -905.2562192 | -897.2767226 | ||||
| r Df Gi | -651.2468855 | -164.4881837 | -22.72237644 | -68.37282622 | -2.710805808 | -909.5410777 | -911.66 |